Temperature-responsive luminescent solar concentrators: tuning energy transfer in a liquid crystalline matrix (2024)

Samenvatting

Temperature-responsive luminescent solar concentrators (LSCs) have been fabricated in which the Förster resonance energy transfer (FRET) between a donor-acceptor pair in a liquid crystalline solvent can be tuned. At room temperatures, the perylene bisimide (PBI) acceptor is aggregated and FRET is inactive; while after heating to a temperature above the isotropic phase of the liquid crystal solvent, the acceptor PBI completely dissolves and FRET is activated. This unusual temperature control over FRET was used to design a color-tunable LSC. The device has been shown to be highly stable towards consecutive heating and cooling cycles, making it an appealing device for harvesting otherwise unused solar energy.

Originele taal-2Engels
Pagina's (van-tot)1030-1033
Aantal pagina's4
TijdschriftAngewandte Chemie - International Edition
Volume57
Nummer van het tijdschrift4
DOI's
StatusGepubliceerd - 22 jan. 2018

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  • publishers versionDefinitieve gepubliceerde versie, 2,09 MBLicentie: CC BY

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    • TU/e MSc Thesis Award 2018 nominee for the Department of Chemical Engineering and Chemistry

      Sol, Jeroen A.H.P. (Ontvanger), 27 sep. 2019

      Prijs: AndersWerk, activiteit of publicatie gerelateerde prijzen (lifetime, best paper, poster etc.)Wetenschappelijk

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    Sol, J. A. H. P., Dehm, V., Hecht, R., Würthner, F., Schenning, A. P. H. J. (2018). Temperature-responsive luminescent solar concentrators: tuning energy transfer in a liquid crystalline matrix. Angewandte Chemie - International Edition, 57(4), 1030-1033. https://doi.org/10.1002/anie.201710487

    Sol, J.A.H.P. ; Dehm, V. ; Hecht, R. et al. / Temperature-responsive luminescent solar concentrators: tuning energy transfer in a liquid crystalline matrix. In: Angewandte Chemie - International Edition. 2018 ; Vol. 57, Nr. 4. blz. 1030-1033.

    @article{a4434b9dc2de440a9a8f2c12c7cd9149,

    title = "Temperature-responsive luminescent solar concentrators: tuning energy transfer in a liquid crystalline matrix",

    abstract = "Temperature-responsive luminescent solar concentrators (LSCs) have been fabricated in which the F{\"o}rster resonance energy transfer (FRET) between a donor-acceptor pair in a liquid crystalline solvent can be tuned. At room temperatures, the perylene bisimide (PBI) acceptor is aggregated and FRET is inactive; while after heating to a temperature above the isotropic phase of the liquid crystal solvent, the acceptor PBI completely dissolves and FRET is activated. This unusual temperature control over FRET was used to design a color-tunable LSC. The device has been shown to be highly stable towards consecutive heating and cooling cycles, making it an appealing device for harvesting otherwise unused solar energy.",

    keywords = "Energy transfer, Fluorescence, Liquid crystals, Luminescent solar concentrators, Perylene dyes",

    author = "J.A.H.P. Sol and V. Dehm and R. Hecht and F. W{\"u}rthner and A.P.H.J. Schenning and M.G. Debije",

    year = "2018",

    month = jan,

    day = "22",

    doi = "10.1002/anie.201710487",

    language = "English",

    volume = "57",

    pages = "1030--1033",

    journal = "Angewandte Chemie - International Edition",

    issn = "0570-0833",

    publisher = "Wiley",

    number = "4",

    }

    Sol, JAHP, Dehm, V, Hecht, R, Würthner, F, Schenning, APHJ 2018, 'Temperature-responsive luminescent solar concentrators: tuning energy transfer in a liquid crystalline matrix', Angewandte Chemie - International Edition, vol. 57, nr. 4, blz. 1030-1033. https://doi.org/10.1002/anie.201710487

    Temperature-responsive luminescent solar concentrators: tuning energy transfer in a liquid crystalline matrix. / Sol, J.A.H.P.; Dehm, V.; Hecht, R. et al.
    In: Angewandte Chemie - International Edition, Vol. 57, Nr. 4, 22.01.2018, blz. 1030-1033.

    Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

    TY - JOUR

    T1 - Temperature-responsive luminescent solar concentrators: tuning energy transfer in a liquid crystalline matrix

    AU - Sol, J.A.H.P.

    AU - Dehm, V.

    AU - Hecht, R.

    AU - Würthner, F.

    AU - Schenning, A.P.H.J.

    AU - Debije, M.G.

    PY - 2018/1/22

    Y1 - 2018/1/22

    N2 - Temperature-responsive luminescent solar concentrators (LSCs) have been fabricated in which the Förster resonance energy transfer (FRET) between a donor-acceptor pair in a liquid crystalline solvent can be tuned. At room temperatures, the perylene bisimide (PBI) acceptor is aggregated and FRET is inactive; while after heating to a temperature above the isotropic phase of the liquid crystal solvent, the acceptor PBI completely dissolves and FRET is activated. This unusual temperature control over FRET was used to design a color-tunable LSC. The device has been shown to be highly stable towards consecutive heating and cooling cycles, making it an appealing device for harvesting otherwise unused solar energy.

    AB - Temperature-responsive luminescent solar concentrators (LSCs) have been fabricated in which the Förster resonance energy transfer (FRET) between a donor-acceptor pair in a liquid crystalline solvent can be tuned. At room temperatures, the perylene bisimide (PBI) acceptor is aggregated and FRET is inactive; while after heating to a temperature above the isotropic phase of the liquid crystal solvent, the acceptor PBI completely dissolves and FRET is activated. This unusual temperature control over FRET was used to design a color-tunable LSC. The device has been shown to be highly stable towards consecutive heating and cooling cycles, making it an appealing device for harvesting otherwise unused solar energy.

    KW - Energy transfer

    KW - Fluorescence

    KW - Liquid crystals

    KW - Luminescent solar concentrators

    KW - Perylene dyes

    UR - http://www.scopus.com/inward/record.url?scp=85038630464&partnerID=8YFLogxK

    U2 - 10.1002/anie.201710487

    DO - 10.1002/anie.201710487

    M3 - Article

    C2 - 29205708

    AN - SCOPUS:85038630464

    SN - 0570-0833

    VL - 57

    SP - 1030

    EP - 1033

    JO - Angewandte Chemie - International Edition

    JF - Angewandte Chemie - International Edition

    IS - 4

    ER -

    Sol JAHP, Dehm V, Hecht R, Würthner F, Schenning APHJ, Debije MG. Temperature-responsive luminescent solar concentrators: tuning energy transfer in a liquid crystalline matrix. Angewandte Chemie - International Edition. 2018 jan. 22;57(4):1030-1033. doi: 10.1002/anie.201710487

    Temperature-responsive luminescent solar concentrators: tuning energy transfer in a liquid crystalline matrix (2024)
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