Samenvatting
Temperature-responsive luminescent solar concentrators (LSCs) have been fabricated in which the Förster resonance energy transfer (FRET) between a donor-acceptor pair in a liquid crystalline solvent can be tuned. At room temperatures, the perylene bisimide (PBI) acceptor is aggregated and FRET is inactive; while after heating to a temperature above the isotropic phase of the liquid crystal solvent, the acceptor PBI completely dissolves and FRET is activated. This unusual temperature control over FRET was used to design a color-tunable LSC. The device has been shown to be highly stable towards consecutive heating and cooling cycles, making it an appealing device for harvesting otherwise unused solar energy.
Originele taal-2 | Engels |
---|---|
Pagina's (van-tot) | 1030-1033 |
Aantal pagina's | 4 |
Tijdschrift | Angewandte Chemie - International Edition |
Volume | 57 |
Nummer van het tijdschrift | 4 |
DOI's | |
Status | Gepubliceerd - 22 jan. 2018 |
Toegang tot document
10.1002/anie.201710487Licentie: CC BY-NC
publishers versionDefinitieve gepubliceerde versie, 2,09 MBLicentie: CC BY
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TU/e MSc Thesis Award 2018 nominee for the Department of Chemical Engineering and Chemistry
Sol, Jeroen A.H.P. (Ontvanger), 27 sep. 2019
Prijs: Anders › Werk, activiteit of publicatie gerelateerde prijzen (lifetime, best paper, poster etc.) › Wetenschappelijk
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Sol, J. A. H. P., Dehm, V., Hecht, R., Würthner, F., Schenning, A. P. H. J. (2018). Temperature-responsive luminescent solar concentrators: tuning energy transfer in a liquid crystalline matrix. Angewandte Chemie - International Edition, 57(4), 1030-1033. https://doi.org/10.1002/anie.201710487
Sol, J.A.H.P. ; Dehm, V. ; Hecht, R. et al. / Temperature-responsive luminescent solar concentrators: tuning energy transfer in a liquid crystalline matrix. In: Angewandte Chemie - International Edition. 2018 ; Vol. 57, Nr. 4. blz. 1030-1033.
@article{a4434b9dc2de440a9a8f2c12c7cd9149,
title = "Temperature-responsive luminescent solar concentrators: tuning energy transfer in a liquid crystalline matrix",
abstract = "Temperature-responsive luminescent solar concentrators (LSCs) have been fabricated in which the F{\"o}rster resonance energy transfer (FRET) between a donor-acceptor pair in a liquid crystalline solvent can be tuned. At room temperatures, the perylene bisimide (PBI) acceptor is aggregated and FRET is inactive; while after heating to a temperature above the isotropic phase of the liquid crystal solvent, the acceptor PBI completely dissolves and FRET is activated. This unusual temperature control over FRET was used to design a color-tunable LSC. The device has been shown to be highly stable towards consecutive heating and cooling cycles, making it an appealing device for harvesting otherwise unused solar energy.",
keywords = "Energy transfer, Fluorescence, Liquid crystals, Luminescent solar concentrators, Perylene dyes",
author = "J.A.H.P. Sol and V. Dehm and R. Hecht and F. W{\"u}rthner and A.P.H.J. Schenning and M.G. Debije",
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Sol, JAHP, Dehm, V, Hecht, R, Würthner, F, Schenning, APHJ 2018, 'Temperature-responsive luminescent solar concentrators: tuning energy transfer in a liquid crystalline matrix', Angewandte Chemie - International Edition, vol. 57, nr. 4, blz. 1030-1033. https://doi.org/10.1002/anie.201710487
Temperature-responsive luminescent solar concentrators: tuning energy transfer in a liquid crystalline matrix. / Sol, J.A.H.P.; Dehm, V.; Hecht, R. et al.
In: Angewandte Chemie - International Edition, Vol. 57, Nr. 4, 22.01.2018, blz. 1030-1033.
Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review
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T1 - Temperature-responsive luminescent solar concentrators: tuning energy transfer in a liquid crystalline matrix
AU - Sol, J.A.H.P.
AU - Dehm, V.
AU - Hecht, R.
AU - Würthner, F.
AU - Schenning, A.P.H.J.
AU - Debije, M.G.
PY - 2018/1/22
Y1 - 2018/1/22
N2 - Temperature-responsive luminescent solar concentrators (LSCs) have been fabricated in which the Förster resonance energy transfer (FRET) between a donor-acceptor pair in a liquid crystalline solvent can be tuned. At room temperatures, the perylene bisimide (PBI) acceptor is aggregated and FRET is inactive; while after heating to a temperature above the isotropic phase of the liquid crystal solvent, the acceptor PBI completely dissolves and FRET is activated. This unusual temperature control over FRET was used to design a color-tunable LSC. The device has been shown to be highly stable towards consecutive heating and cooling cycles, making it an appealing device for harvesting otherwise unused solar energy.
AB - Temperature-responsive luminescent solar concentrators (LSCs) have been fabricated in which the Förster resonance energy transfer (FRET) between a donor-acceptor pair in a liquid crystalline solvent can be tuned. At room temperatures, the perylene bisimide (PBI) acceptor is aggregated and FRET is inactive; while after heating to a temperature above the isotropic phase of the liquid crystal solvent, the acceptor PBI completely dissolves and FRET is activated. This unusual temperature control over FRET was used to design a color-tunable LSC. The device has been shown to be highly stable towards consecutive heating and cooling cycles, making it an appealing device for harvesting otherwise unused solar energy.
KW - Energy transfer
KW - Fluorescence
KW - Liquid crystals
KW - Luminescent solar concentrators
KW - Perylene dyes
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Sol JAHP, Dehm V, Hecht R, Würthner F, Schenning APHJ, Debije MG. Temperature-responsive luminescent solar concentrators: tuning energy transfer in a liquid crystalline matrix. Angewandte Chemie - International Edition. 2018 jan. 22;57(4):1030-1033. doi: 10.1002/anie.201710487